JOPSS - Search Results

Journal Articles

Quantitative analysis of microstructure evolution, stress partitioning and thermodynamics in the dynamic transformation of Fe-14Ni alloy

Li, L.*; Miyamoto, Goro*; Zhang, Y.*; Li, M.*; Morooka, Satoshi; Oikawa, Katsunari*; Tomota, Yo*; Furuhara, Tadashi*

Journal of Materials Science & Technology, 184, p.221 - 234, 2024/06

https://doi.org/10.1016/j.jmst.2023.10.037

Times Cited Count：0 Percentile：0(Materials Science, Multidisciplinary)

Journal Articles

Production and compilation of charge changing cross sections of ion-atom and ion-molecule collisions

Imai, Makoto*; Shirai, Toshizo*; Saito, Manabu*; Haruyama, Yoichi*; Ito, Akio*; Imanishi, Nobutsugu*; Fukuzawa, Fumio*; Kubo, Hirotaka

Journal of Plasma and Fusion Research SERIES, Vol.7, p.323 - 326, 2006/00

no abstracts in English

Journal Articles

Characterization of rust layer formed on Fe, Fe-Ni and Fe-Cr alloys exposed to Cl-rich environment by Cl and Fe K-edge XANES measurements

Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro

Materials Transactions, 46(2), p.329 - 336, 2005/02

https://doi.org/10.2320/matertrans.46.329

Times Cited Count：28 Percentile：80.32(Materials Science, Multidisciplinary)

Chloride in atmosphere considerably reduces the corrosion resistance of conventional weathering steel containing a small amount of Cr. Ni is an effective anticorrosive element for improving the corrosion resistance of steel in a Cl-rich environment. In order to clarify the structure of the protective rust layer of weathering steel, Cl and Fe K-edge X-ray absorption near edge structure (XANES) spectra of atmospheric corrosion products (rust) formed on Fe, Fe-Ni and Fe-Cr alloys exposed to Cl-rich atmosphere were measured. The Fe K-XANES measurements enable the characterization of a mixture of iron oxides such as rust. The chemical composition of the rust was determined by performing pattern fitting of the measured spectra. All the rust is composed mainly of goethite, akaganite, lepidocrocite and magnetite. Among these iron oxides, akaganite in particular is the major component in the rust. Additionally, the amount of akaganite in the rust of Fe-Ni alloy is much greater than that in rust of Fe-Cr alloy. Akaganite is generally considered to facilitate the corrosion of steel, but our results indicate that akaganite in the rust of Fe-Ni alloy is quantitatively different from that in rust of Fe-Cr alloy and does not facilitate the corrosion of steel. The shoulder peak observed in Cl K-XANES spectra reveals that the rust contains a chloride other than akaganite. The energy of the shoulder peak does not correspond to that of any well-known chlorides. In the measured spectra, there is no proof that Cl, by combining with the alloying element, inhibits the alloying element from acting in corrosion resistance. The shoulder peak appears only when the content of the alloying element is lower than a certain value. This suggests that the generation of the unidentified chloride is related to the corrosion rate of steel.

Journal Articles

Cl K-edge XANES spectra of atmospheric rust on Fe, Fe-Cr and Fe-Ni alloys exposed to saline environment

Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro

Materials Transactions, 45(12), p.3356 - 3359, 2004/12

https://doi.org/10.2320/matertrans.45.3356

Times Cited Count：10 Percentile：53.05(Materials Science, Multidisciplinary)

Cl K-edge XANES measurements of atmospheric corrosion products (rust) formed on Fe, Fe-Ni and Fe-Cr alloys in chloride pollution have been performed using synchrotron radiation in order to clarify roles of anticorrosive alloying elements and of Cl in the corrosion resistance of weathering steel. The spectra of binary alloys show a shoulder structure near the absorption edge. The intensity of the shoulder peak depends on the kind and amount of the alloying element, whereas the energy position is invariant. This indicates that Cl is not combined directly with alloying elements in the rust.

Journal Articles